Case study·Standard multi-step (3/5)·No calculator

Difficulty guide

The label describes the problem, not your ability.

1/5 - Foundational

Warm-up setup; checks one basic idea.

2/5 - Routine exam skill

Normal syllabus skill; usually one main rule or interpretation.

3/5 - Standard multi-step

Exam-style problem with multiple steps or a common trap.

4/5 - Hard exam skill

High-end exam problem; combines methods carefully.

5/5 - Challenge

Stretch problem beyond normal exam pressure.

Question

Three bases are labelled P, Q and R. P is aniline, Q is cyclohexylamine, and R is p-nitroaniline. Equal amounts are shaken separately with dilute hydrochloric acid and then compared for tendency to form ammonium salts.
Total: 4 marks

(a) Which base is strongest? (1 mark)

(b) Which base is weakest? (1 mark)

(c) Explain the role of resonance in P. (1 mark)

(d) Explain the role of the nitro group in R. (1 mark)

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cbse-chemistry-12.u9-amines.t9-3.case.005

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