Long answer·Hard exam skill (4/5)·No calculator

Difficulty guide

The label describes the problem, not your ability.

1/5 - Foundational

Warm-up setup; checks one basic idea.

2/5 - Routine exam skill

Normal syllabus skill; usually one main rule or interpretation.

3/5 - Standard multi-step

Exam-style problem with multiple steps or a common trap.

4/5 - Hard exam skill

High-end exam problem; combines methods carefully.

5/5 - Challenge

Stretch problem beyond normal exam pressure.

Question

Three isomeric alcohols A, B and C have molecular formula C4H10O\mathrm{C_4H_{10}O}. A gives immediate turbidity with Lucas reagent and resists ordinary oxidation. B gives a yellow iodoform precipitate and is oxidised to a ketone. C gives no immediate Lucas turbidity, gives no iodoform precipitate, and is oxidised to butanoic acid. Identify A, B and C.
Total: 3 marks

(a) Identify A and give the Lucas-test reason. (1 mark)

(b) Identify B and give the iodoform/oxidation reason. (1 mark)

(c) Identify C and give the oxidation reason. (1 mark)

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cbse-chemistry-12.u7.t7-3.laq.004

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