Case study·Standard multi-step (3/5)·No calculator

Difficulty guide

The label describes the problem, not your ability.

1/5 - Foundational

Warm-up setup; checks one basic idea.

2/5 - Routine exam skill

Normal syllabus skill; usually one main rule or interpretation.

3/5 - Standard multi-step

Exam-style problem with multiple steps or a common trap.

4/5 - Hard exam skill

High-end exam problem; combines methods carefully.

5/5 - Challenge

Stretch problem beyond normal exam pressure.

Question

Acetone and chloroform form a non-ideal solution. The unlike molecular attractions become stronger because of specific interaction between the two components.
Total: 4 marks

(a) State whether the solution shows positive or negative deviation from Raoult's law. (1 mark)

(b) Compare its observed vapour pressure with the ideal value. (1 mark)

(c) State the type of azeotrope expected at the extreme composition, if an azeotrope is formed. (1 mark)

(d) Give the molecular reason for the deviation. (1 mark)

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