Case study·Standard multi-step (3/5)·No calculator

Difficulty guide

The label describes the problem, not your ability.

1/5 - Foundational

Warm-up setup; checks one basic idea.

2/5 - Routine exam skill

Normal syllabus skill; usually one main rule or interpretation.

3/5 - Standard multi-step

Exam-style problem with multiple steps or a common trap.

4/5 - Hard exam skill

High-end exam problem; combines methods carefully.

5/5 - Challenge

Stretch problem beyond normal exam pressure.

Question

The figure shows numbered positions around a substituted benzene ring. Use the numbering to apply ortho, meta and para definitions; decide the directing effect from the substituent.
Total: 5 marks

(a) How many ortho positions are available relative to X? (1 mark)

(b) How many meta positions are available relative to X? (1 mark)

(c) If X is CH3\mathrm{CH_3}, which numbered positions and position types are favoured in nitration? (2 marks)

(d) If X is NO2\mathrm{NO_2}, which numbered positions and position type are favoured in further nitration? (1 mark)

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cbse-chemistry-11.u9.t9-5.case.005

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