Case study·Standard multi-step (3/5)·No calculator

Difficulty guide

The label describes the problem, not your ability.

1/5 - Foundational

Warm-up setup; checks one basic idea.

2/5 - Routine exam skill

Normal syllabus skill; usually one main rule or interpretation.

3/5 - Standard multi-step

Exam-style problem with multiple steps or a common trap.

4/5 - Hard exam skill

High-end exam problem; combines methods carefully.

5/5 - Challenge

Stretch problem beyond normal exam pressure.

Question

A lab prepares two solutions. Solution P contains 0.10 M0.10\text{ M} acetic acid and 0.10 M0.10\text{ M} sodium acetate. Solution Q contains only 0.10 M0.10\text{ M} acetic acid. Small amounts of acid and base are added separately to samples of both solutions.
Total: 5 marks

(a) Which solution is a buffer? (1 mark)

(b) If pKa=4.76pK_a=4.76, estimate the initial pH of P. (2 marks)

(c) Which solution shows larger pH change on small acid addition? (1 mark)

(d) Give the chemical reason. (1 mark)

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